High surface area and Z' in a thermally stable 8-fold polycatenated hydrogen-bonded framework.
نویسندگان
چکیده
1,3,5-Tris(4-carboxyphenyl)benzene assembles into an intricate 8-fold polycatenated assembly of (6,3) hexagonal nets formed through hydrogen bonds and π-stacking. One polymorph features 56 independent molecules in the asymmetric unit, the largest Z' reported to date. The framework is permanently porous, with a BET surface area of 1095 m(2) g(-1) and readily adsorbs N2, H2 and CO2.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 58 شماره
صفحات -
تاریخ انتشار 2015